Chiral g-lactones are prevalent organic architectures {found|discovered|identified|located} {in a|inside a|within a} {large|big|huge|massive|substantial|significant} array of {natural|all-natural|organic} {products|goods|items|merchandise|solutions}. {In this|Within this} {work|function|perform|operate}, we disclose the {development|improvement} of a modified catalytic {system|method|program|technique} {utilizing|using} a commercially {available|accessible|obtainable|offered|readily available|out there} Cu-phosphite catalyst for the diastereoselective reductive coupling of chiral allenamides and ketones to afford chiral g-lactone precursors in 80:20 to 99:1 dr. Buy935845-20-8 Buy731810-57-4 PMID:24507727
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