A sustainable future {requires|demands|needs|calls for} {highly|extremely|very|hugely} {efficient|effective} {energy|power} conversion and storage processes, {where|exactly where} electrocatalysis plays a {crucial|essential|vital|critical|important} {role|function|part}. The activity of an electrocatalyst is governed by the binding {energy|power} towards the reaction intermediates, {while|whilst|although|even though|when|though} the scaling relationships {prevent|stop|avoid|avert|protect against} the improvement of a catalytic {system|method|program|technique} {over|more than} its volcano-plot limits. To overcome these limitations, unconventional {methods|techniques|strategies|approaches|procedures|solutions} {that are|which are|which can be|which might be|that happen to be} not {fully|totally|completely} determined by the surface binding {energy|power} {can be|may be|could be|might be|is often|is usually} {helpful|useful|beneficial|valuable}. {Here|Right here}, we use organic chiral molecules, i.e., hetero-helicenes, to {boost|increase|enhance} the oxygen evolution reaction (OER) by ca. 131.{5|five} % ({at the|in the} {potential|possible|prospective} of 1.65 V vs. RHE) at state-of-the-art 2D catalysts {via|by way of|through|by means of} a spin-polarization mechanism. Our {results|outcomes|final results|benefits} show that chiral molecule-functionalization is {able to|in a position to} {increase|improve|boost|enhance|raise} the OER activity of catalysts beyond the volcano limits. A guideline for optimizing the catalytic activity {via|by way of|through|by means of} chiral molecular functionalization of hybrid 2D electrodes is {given|offered|provided}. 1020174-04-2 Price 3-(2-Methoxyethyl)azetidine Chemscene PMID:26446225
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