The exploitation of high-capacity conversion-type {materials|supplies|components} {such as|like|including|for example|for instance|which include} sulfur in solid-state secondary batteries {is a|is really a|is actually a|can be a|is often a|is usually a} dream {combination|mixture} for {achieving|reaching|attaining} {improved|enhanced} battery {safety|security} and {high|higher} {energy|power} density {in the|within the|inside the} push towards a sustainable future. {Yet|However|But}, the {exact|precise} rate-limiting step, bottlenecking {further|additional} {development|improvement} of solid-state lithium-sulfur batteries, has not been determined. {Here|Right here}, we {directly|straight} visualize the spatial distribution of lithium {via|by way of|through|by means of} neutron imaging {during|throughout|in the course of|for the duration of|through} operation and show that sluggish macroscopic ion transport {within|inside} the composite cathode is rate-limiting. Observing a reaction front propagating {from the|in the} separator side towards the {current|present|existing} collector confirms detrimental influences of a low {effective|efficient|successful|powerful|productive|helpful} ionic conductivity. {Furthermore|Moreover|In addition|Additionally}, irreversibly concentrated lithium {in the|within the|inside the} vicinity {of the|from the|in the|on the|with the|of your} {current|present|existing} collector, revealed {via|by way of|through|by means of} state-of-charge-dependent tomography, highlights a hitherto-overlooked loss mechanism triggered by sluggish {effective|efficient|successful|powerful|productive|helpful} ionic transport {within|inside} a composite cathode. This discovery {will be|will probably be|will likely be|is going to be|might be|are going to be} a cornerstone for future {research|study|analysis|investigation} on solid-state batteries, irrespective {of the|from the|in the|on the|with the|of your} {type|kind|sort|variety|form} of active material. GPhos Pd G6 TES Chemical name 6-Bromobenzo[cd]indol-2(1H)-one manufacturer PMID:23543429

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