Regiocontrolled Allylic Functionalization of Internal Alkene {via|by way of|through|by means of} Selenium-pi-Acid Catalysis Guided by Boron Substitution

The selenium-pi-acid-catalysis has received {increasing|growing|escalating|rising} {attention|interest|focus|consideration} as {powerful|potent|effective|strong|highly effective} tools for olefin functionalization, {but the|however the} regioselectivity is {often|frequently|usually|typically|generally|normally} problematic. Reported herein {is a|is really a|is actually a|can be a|is…

Illuminating mechanochemical reactions by combining real-time fluorescence emission monitoring and periodic time-dependent density-functional calculations

We {provide|offer|supply|give|present|deliver} a proof-of-principle demonstration {of the|from the|in the|on the|with the|of your} {first|initial|very first|1st|initially} dual-spectroscopic {method|technique|approach|strategy|system|process} for direct and real-time observation of mechanochemical reactions by ball milling, supported by high-level…

Electronic Spectroscopy of Isolated DNA Polyanions

In {solution|answer|remedy|resolution|option}, UV-vis spectroscopy is {often|frequently|usually|typically|generally|normally} {used|utilized|employed|utilised|applied|made use of} to investigate structural {changes|modifications|adjustments|alterations} in biomolecules (i.e., nucleic acids), owing to {changes|modifications|adjustments|alterations} {in the|within the|inside the} {environment|atmosphere} of their chromophores (i.e.,…

Synergistic Experimental and Computational Investigation {of the|from the|in the|on the|with the|of your} Bioorthogonal Reactivity of Substituted Aryltetrazines

Tetrazines (Tz) {have been|happen to be|have already been} applied as bioorthogonal agents for {various|numerous|different|a variety of|several|many} biomedical applications {including|such as|which includes|like} pretargeted imaging approaches. In radioimmunoimaging, pretargeting increases the target-to-background…