Electrochemical approaches hold {promise|guarantee} for energy-efficient and modular carbon dioxide (CO2) separation systems {that can|that may|that will|that could|which will|which can} make direct use of renewably-generated {electricity|electrical energy}. {Here|Right here} we employ a thermodynamic modeling {approach|method|strategy} to estimate the upper {performance|overall performance|efficiency|functionality} bounds of CO2 separation processes that use soluble, redox-active capture species. We contemplate the {impact|influence|effect} of tunable molecular and electrolyte properties {on the|around the} thermodynamic and faradaic efficiencies of {four|4} characteristic {system|method|program|technique} configurations. We {find|discover|locate|uncover|come across|obtain} a tradeoff {between|in between|among|amongst|involving} these efficiency metrics, and propose {a new|a brand new} metric, the combined efficiency, {that can be|that may be} {used|utilized|employed|utilised|applied|made use of} to {further|additional} {explore|discover} this tradeoff and {identify|determine|recognize} desirable {property|home|house} sets that balance {energy|power} and {materials|supplies|components} {requirements|specifications|needs}. Subsequently, we {determine|figure out|decide|establish|ascertain|identify} {effective|efficient|successful|powerful|productive|helpful} CO2 binding affinities of redox-active capture molecules and demonstrate how these values are dependent upon molecular properties, {system|method|program|technique} format, and operating {conditions|circumstances|situations}. {Overall|General|All round}, this analytical framework {can help|might help|will help|can assist} guide molecular discovery and electrolyte engineering {in this|within this} emerging field by {providing|supplying|offering|delivering|giving} insight into target material properties. 1273577-11-9 site Bis(pyridine)iodonium tetrafluoroborate Formula PMID:36628218

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