Non-centrosymmetric single-crystal metal-organic frameworks (MOF) are promising candidates for phase-matched nonlinear optical communication, but {typical|common|standard} hydrothermal synthesis produces {small|little|tiny|modest|smaller|compact} crystals with {relatively|fairly|comparatively|reasonably|somewhat} low transmittance and poor phase matching. We study the {effect|impact} {of the|from the|in the|on the|with the|of your} metal-to-ligand molar ratio and reaction pH {on the|around the} hydro-thermal synthesis {of the|from the|in the|on the|with the|of your} non-centrosymmetric Zn(3-ptz){2|two} and Zn(OH)(3-ptz) MOFs with in-situ ligand formation. In acidic environments, we {find that|discover that} decreasing the {amount|quantity} of ligand {below|beneath|under} the stoichiometric molar ratio 1:{2|two} also produces {highly|extremely|very|hugely} transparent single-crystal octahedrons of Zn(3-ptz){2|two}. In alkaline environments, we {obtain|acquire|get|receive} {long|lengthy|extended} rod-like Zn(OH)(3-ptz) crystals whose length exceeds {previous|prior|earlier|preceding} reports by {up to|as much as} {four|4} orders of magnitude. {Potential|Possible|Prospective} applications {of these|of those} {results|outcomes|final results|benefits} {in the|within the|inside the} {development|improvement} of MOF-based nonlinear optical devices are discussed. Buy3-(tert-Butyl)cyclohexanone Formula of 1210834-55-1 PMID:23539298
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