{Using|Utilizing|Making use of|Employing|Working with|Applying} metal-organic cages (MOCs) as preformed supermolecular building-blocks (SBBs) {is a|is really a|is actually a|can be a|is often a|is usually a} {powerful|potent|effective|strong|highly effective} {strategy|technique|method|approach|tactic} to {design|style|design and style} functional metal-organic frameworks (MOFs) with {control|manage|handle} {over|more than} the pore architecture and connectivity. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that}, introducing chemical complexity {into the|in to the} network {via|by way of|through|by means of} this route is {limited|restricted} as most methodologies {focus|concentrate} on only {one|1|a single|one particular} {type of|kind of|sort of|form of|style of|variety of} MOC {as the|because the} building-block. Herein we present the pairwise linking of MOCs as a {design|style|design and style} {approach|method|strategy} to introduce defined chemical complexity into porous {materials|supplies|components}. Our methodology exploits preferential Rh-aniline coordination and stoichiometric {control|manage|handle} to rationally {link|hyperlink} Cu4L4 and Rh4L4 MOCs into chemically {complex|complicated}, {yet|however|but} {extremely|very|incredibly|really|particularly|exceptionally} well-defined crystalline solids. This {strategy|technique|method|approach|tactic} is {expected|anticipated} to open up {significant|substantial|considerable|important} new possibilities to {design|style|design and style} bespoke multi-functional {materials|supplies|components} with atomistic {control|manage|handle} {over|more than} the {location|place} and ordering of chemical functionalities. Formula of 790667-43-5 Price of 183070-44-2 PMID:35116795
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