CO2 electrochemical reduction to formate has emerged as {one of the|among the|one of many|one of several|among the list of|on the list of} promising routes for CO2 conversion to {useful|helpful|beneficial|valuable} {chemicals|chemical substances|chemical compounds} and renewable {energy|power} storage. Palladium has been shown {to make|to create|to produce} formate {with a|having a|using a} {high|higher} selectivity at minimal overpotential. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that}, production of CO as a minor {product|item|solution} {quickly|rapidly|swiftly|speedily|promptly|immediately} deactivates the catalyst {during|throughout|in the course of|for the duration of|through} extended electrolysis. {Here|Right here}, we present nanoporous Pd alloys (np-PdX) formed by electrochemical dealloying of Pd15X85 alloys (X = Co, Ni, Cu, and Ag) as active {free|totally free|free of charge|cost-free|absolutely free|no cost} standing electrocatalysts with {high|higher} formate selectivity and superior CO poisoning tolerance. {Rate|Price} of deactivation {under|below|beneath} {constant|continuous|continual} {potential|possible|prospective} electrolysis, {due to|because of|as a result of|on account of|resulting from|as a consequence of} CO passivation, is strongly correlated {to the|towards the|for the} identity {of the|from the|in the|on the|with the|of your} transition metal alloying {component|element}. We purport that this composition dependent behavior is {due to|because of|as a result of|on account of|resulting from|as a consequence of} the induced electronic {changes|modifications|adjustments|alterations} {in the|within the|inside the} active Pd surface, affecting {both|each} the CO adsorption strength {and the|and also the|as well as the|along with the|plus the} {near|close to} surface hydrogen solubility which can {impact|influence|effect} the adsorption strength of active/inactive intermediates and reaction selectivity. Free-standing np-PdCo is {found|discovered|identified|located} to exhibit {high|higher} areal formate partial {current|present|existing} densities, > 40 mA cm-2, with superior CO poisoning tolerance and minimal active {area|region|location} loss at cathodic potentials, demonstrating the utility {of these|of those} {materials|supplies|components} for selective and {stable|steady} CO2 electrolysis6144-78-1 structure Formula of APhos Pd G3 PMID:23415682
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