{A new|A brand new} Ru3(CO)12-catalyzed directed alkenylation of 2-carboxaldimine-heterocyclopentadienes has been {accomplished|achieved}. This {process|procedure|method|approach|course of action} {allows|enables|permits|makes it possible for} to couple furan, pyrrole, indole and thiophene 2-carboxaldimines with electron-poor alkenes {such as|like|including|for example|for instance|which include} acrylates, vinylsulfones, and styrenes. This regio- and chemoselective oxidative C–H coupling {does not|doesn’t|will not} {require|need|demand|call for} the presence of an {additional|extra|further|added|more} sacrificial oxidant. Density functional theory (DFT) calculations {allowed|permitted} to propose a mechanism and unveiled the nature {of the|from the|in the|on the|with the|of your} H2 acceptor. Formula of G0-C14 133186-53-5 site PMID:23916866
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