{Despite|Regardless of|In spite of} the {many|numerous|several|a lot of|quite a few|lots of} {recent|current} advances in exploiting stoichiometric charge-transfer complexes in visible light promoted single-electron redox reactions, catalytic approaches to charge-transfer {complex|complicated} formation {remain|stay} {limited|restricted}. This report describes the radical perfluoroalkylation of electron-rich (hetero)arenes and iodoperfluoroalkylation of alkenes and alkynes promoted by a substituted hydroquinone catalyst. Mechanistic and computational {studies|research} indicate that the reaction is initiated by the formation of a visible light absorbing halogen bonding {complex|complicated} {between|in between|among|amongst|involving} the hydroquinone catalyst {and the|and also the|as well as the|along with the|plus the} perfluoroalkyl iodide radical precursor. 1,3,6,8-Tetrabromopyrene Order BuyD-Desthiobiotin PMID:23695992
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