Acid-driven multiphase chemistry of isoprene epoxydiols (IEPOX), a {key|important|crucial|essential} isoprene oxidation {product|item|solution}, with inorganic sulfate aerosol yields substantial amounts of secondary organic aerosol (SOA) {through|via|by means of|by way of} the formation of organosulfur. The extent and implications of inorganic-to-organic sulfate conversion, {however|nevertheless|nonetheless|even so|on the other hand|having said that}, are unknown. Herein, we reveal that {extensive|in depth|substantial|comprehensive} consumption of inorganic sulfate {occurs|happens}, which increases {with the|using the|with all the|together with the} IEPOX-to-inorganic sulfate ratio (IEPOX:Sulfinorg), as determined by laboratory and field measurements. We {further|additional} demonstrate that organosulfur {greatly|significantly|tremendously|drastically|considerably} modifies {critical|crucial|vital|essential|important} aerosol properties, {such as|like|including|for example|for instance|which include} acidity, morphology, viscosity, and phase state. These new mechanistic insights reveal that {changes|modifications|adjustments|alterations} in SO2 emissions, {especially|particularly|specifically|specially|in particular} in isoprene-dominated environments, will {significantly|considerably|substantially|drastically} alter biogenic SOA physicochemical properties. Consequently, IEPOX:Sulfinorg will play a central {role|function|part} in understanding historical climate and {determining|figuring out} future impacts of biogenic SOA on {global|international|worldwide} climate and air {quality|high quality|top quality|good quality|excellent|high-quality}. Buy1,3,5-Tri(pyridin-4-yl)benzene 7-Chloropyrido[3,4-b]pyrazine uses PMID:23907521
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