The rational {design|style|design and style} of disordered frameworks {is an|is definitely an} {appealing|attractive} route to target functional {materials|supplies|components}. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that}, intentional realisation of such {materials|supplies|components} relies on our {ability to|capability to} readily characterise and quantify structural disorder. {Here|Right here}, we use multivariate {analysis|evaluation} of pair distribution functions to fingerprint and quantify the disorder {within|inside} a series of compositionally identical metal–organic frameworks, possessing {different|various|distinct|diverse|unique|distinctive} crystalline, disordered, and amorphous structures. We {find|discover|locate|uncover|come across|obtain} this {approach|method|strategy} can {provide|offer|supply|give|present|deliver} {powerful|potent|effective|strong|highly effective} insight {into the|in to the} kinetics and mechanism of structural collapse that {links|hyperlinks} these {materials|supplies|components}. Our methodology {is also|can also be} extended to {a very|a really|an extremely|an incredibly} {different|various|distinct|diverse|unique|distinctive} {system|method|program|technique}, namely the melting of a zeolitic imidazolate framework, to demonstrate the {potential|possible|prospective} generality of this {approach|method|strategy} across {many|numerous|several|a lot of|quite a few|lots of} {areas|locations|places|regions} of disordered structural chemistry. 2820536-71-6 Chemical name Methyl 6-formylnicotinate Chemscene PMID:23892746
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