The indolocarbazole derivatives has been shown {great|fantastic|excellent|wonderful|good|terrific} potentials as {one of the|among the|one of many|one of several|among the list of|on the list of} {key|important|crucial|essential} {important|essential|crucial|critical|significant|vital} compounds {in the|within the|inside the} field of organic electronics owing to their {attractive|appealing|desirable|eye-catching} structural and electrical properties. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that}, {studies|research} that {directly|straight} and systematically introduce indolocarbazole unit into MOFs are {still|nonetheless|nevertheless} lacking. Herein, we reported the synthesis of {6|six},12-di(hetero)aryl substituted {5|five},{6|six},11,12-tetrahyroindolo[3,2-b]carbazole synthetic motifs {in a|inside a|within a} facile way. The {potential|possible|prospective} {of these|of those} synthetic motifs as {building|developing|creating|constructing} block for porous {materials|supplies|components} fabrication is unveiled {through|via|by means of|by way of} the preparation of Zn-MOF-ICZ and UiO-68-ICZ {by using|by utilizing} {5|five},{6|six},11,12-tetrahyroindolo[3,2-b]carbazole terminated with dicarboxylate acid. The resultant Zn-MOF-ICZ and UiO-68-ICZ {feature|function} {5|five},11-dihyroindolo[3,2-b]carbazole unit {as a result of|because of} in-situ oxidative dehydrogenation, which was confirmed by 1H NMR and single crystal X-ray diffraction study. The {successful|effective|productive|profitable|prosperous|thriving} {construction|building} {of these|of those} MOFs indicated the {powerful|potent|effective|strong|highly effective} of {6|six},12-di(hetero)aryl substituted {5|five},{6|six},11,12-tetrahyroindolo[3,2-b]carbazole unit for porous {materials|supplies|components} synthesis and this {provides|offers|gives|supplies|delivers} a broad platforms for {potential|possible|prospective} applications investigation {considering|contemplating|thinking about|taking into consideration|thinking of} their fine optical properties. 846548-44-5 Chemscene 2-(2-Bromoethyl)oxirane web PMID:24423657

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