We {put|place} forth a {simple|easy|straightforward|basic|uncomplicated|very simple} and {yet|however|but} {practical|sensible} theoretical model generalized from Raoult’s law and Henry’s law and show that {it can|it could|it may|it might} be {reduced|decreased|lowered} to these two laws {under|below|beneath} limiting {conditions|circumstances|situations}. The model entertains a hybrid parameter h_B with activity coefficient bundled into it, which smoothly bridges the p_B^* and K_B coefficients in Raoult’s law and Henry’s law. The {value|worth} of h_B falls {in the|within the|inside the} interval of [K_B, p_B^*] or [p_B^*, K_B] {in the|within the|inside the} case of {negative|unfavorable|damaging|adverse} or {positive|good|optimistic|constructive} deviation from Raoult’s law, respectively. We uncover an overlapping rule for the ranges of h_A and h_B, which binary mixtures {must|should|need to|have to|ought to|will have to} obey to {form|type|kind} azeotropes. We also {provide|offer|supply|give|present|deliver} {straightforward|simple} {ways to|methods to|approaches to|strategies to|solutions to} analyze the characteristic mole fraction and {pressure|stress} for azeotropes and {to understand|to know} the relative positions of vapor composition curves with respect {to the|towards the|for the} liquid counterparts. We rely heavily on experimental {data|information} {available|accessible|obtainable|offered|readily available|out there} {in the|within the|inside the} literature for representative binary mixtures with {both|each} {negative|unfavorable|damaging|adverse} and {positive|good|optimistic|constructive} deviations from Raoult’s law to illustrate the algebraic derivations. The {knowledge|understanding|information|expertise|know-how} gained is {useful|helpful|beneficial|valuable} {in the|within the|inside the} {analysis|evaluation} of experimental {data|information} from vapor-liquid equilibrium measurements and possess pedagogical merit in {various|numerous|different|a variety of|several|many} relevant fields. 779353-64-9 web Formula of 1,4-Dihydro-1,4-methanonaphthalene PMID:34645436
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