Nature possesses a {powerful|potent|effective|strong|highly effective} {ability|capability|capacity|potential} to assemble {multiple|numerous|several|a number of|many|various} {complex|complicated} structures to fabricate hierarchical biological structures {in a|inside a|within a} living-assembled way. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that}, {it is|it’s|it really is|it truly is|it can be|it is actually} {still|nonetheless|nevertheless} {a huge|an enormous|a massive} challenge for artificial systems to fabricate and characterize hierarchical living assemblies with well-defined and controllable but {complex|complicated} structures. {In this|Within this} {work|function|perform|operate}, we proposed {a new|a brand new} {concept|idea|notion} for the fabrication of multiblock fluorescent microcolumns, which relies {on the|around the} cooperation {between|in between|among|amongst|involving} the controllable host–guest complexation {based on|according to|depending on|determined by} cucurbit[8]uril (CB[8]) {and the|and also the|as well as the|along with the|plus the} living assembly of nanotubular supramolecular polymers composed of CB[8] and NaBr in aqueous {solution|answer|remedy|resolution|option}. {By using|By utilizing} the complexation of CB[8] with {different|various|distinct|diverse|unique|distinctive} guest numbers of luminogens with aggregation-induced emission (AIEgens) {characteristics|traits|qualities}, {and the|and also the|as well as the|along with the|plus the} {difference|distinction} in affinity {between|in between|among|amongst|involving} CB[8] and {different|various|distinct|diverse|unique|distinctive} {types of|kinds of|varieties of|forms of|sorts of} AIEgens, the concentration-controlled and self-sorting-controlled sequential living assembly are realized, respectively. Correspondingly, multiblock fluorescent microcolumns with {different|various|distinct|diverse|unique|distinctive} fluorescence emission are fabricated, {and the|and also the|as well as the|along with the|plus the} molecular structure of {each|every|each and every|every single} fluorescent block is analyzed by single crystal X-ray diffraction measurement. {In addition|Additionally|Furthermore|Moreover|Also}, the living assembly of multiblock fluorescent microcolumns is visualized, understood, and regulated {with the|using the|with all the|together with the} {aid|help} of AIEgens. The {method|technique|approach|strategy|system|process} {developed|created} {here|right here} is {expected|anticipated} {to be|to become} extended to {more|much more|a lot more|far more|additional|extra} guest molecules of CB[8] {and also|as well as} {provides|offers|gives|supplies|delivers} a referential crystallization {method|technique|approach|strategy|system|process} for CB[8]-based complexes. 1019111-84-2 site 1210830-60-6 Formula PMID:36628218
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