Structure-sensitive reactions involving the Mars and van Krevelen mechanism over metal and metal oxide catalysts are ubiquitous in reaction kinetics and engineering. The kinetic equations of such reactions are re-written to account for modern operando spectroscopy and microscopy observations. Emphasis is placed on reactions with nucleophilic (lattice) oxygen, oxygen reduction reversibility, an interconversion scheme, non-linear water adsorption, remote-control model, and non-uniform sites. The multiplicity of propane conversion over MoVTeNbOx catalysts is proven through a combination of non-linear competitive water adsorption, the presence of multiple active sites, a re-structuring active site, and oxygen adsorption. The modified remote-control kinetics for the Mars and van Krevelen mechanism can account for the observations of steady-state multiplicities and hysteresis. The results have implications for improving catalytic activity, reducing operating process costs, and active site engineering of selective oxidation catalysis. Ethyl 2,2,2-triethoxyacetate Purity 1258874-29-1 Chemical name PMID:24013184
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