The photoluminescence (PL) of organolead halideperovskites (OHPs) is sensitive to its surface {conditions|circumstances|situations}, {especially|particularly|specifically|specially|in particular} surfacedefect states, {making|creating|producing|generating} the PL of {small|little|tiny|modest|smaller|compact} OHP crystals {an effective|an efficient} {way to|method to|approach to|strategy to|technique to|solution to} report theirsurface states. {At the|In the} ensemble level, when averaging {a lot of|lots of|plenty of|a great deal of|many|loads of} nanocrystals,the photoexcitation of OHP nanorods {under|below|beneath} inert nitrogen (N2) atmosphereleads to PL decline, {while|whilst|although|even though|when|though} subsequent exposure to oxygen (O2){results|outcomes|final results|benefits} to reversible PL recovery. {At the|In the} single-particle level, {individual|person} OHPnanorods photoblinks, whose probability is dependent on {both|each} the excitationintensity {and the|and also the|as well as the|along with the|plus the} O2 concentration. Combining the two sets ofinformation, {we are|we’re} {able to|in a position to} quantitatively evaluating the interaction {between|in between|among|amongst|involving} asingle surface defect {and a|along with a|as well as a|plus a|and also a|in addition to a} single O2 molecule {using|utilizing|making use of|employing|working with|applying} a kineticmodel. This model {provides|offers|gives|supplies|delivers} {fundamental|basic} insights that could {help|assist|aid|support|enable|assistance} reconcile thecontradicting views {on the|around the} interactions of molecular O2 with OHPmaterials and {help|assist|aid|support|enable|assistance} {design|style|design and style} a {suitable|appropriate} OHP interface {for a|to get a|for any} {variety|selection|assortment|range|wide variety} ofapplications in photovoltaics and optoelectronics. 913820-87-8 structure 6-Bromo-3-chloroisoquinoline web PMID:23771862

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