We report experimental and computational {evidence|proof} for nitrogen–fluorine halogen bonding in Ag(I)-initiated radical C–H fluorinations. {Simple|Easy|Straightforward|Basic|Uncomplicated|Very simple} pyridines {form|type|kind} + halogen bonds with Selectfluor to facilitate single-electron reduction by catalytic…
The oxidation of alkenes by high-valent iron-oxo active species {normally|usually|typically|generally|commonly|ordinarily} {leads to|results in} the formation {of the|from the|in the|on the|with the|of your} corresponding epoxides. {Rarely|Seldom|Hardly ever}, carbonyl compounds are observed…
{Once|As soon as|When|After} the optical, electronic or photocatalytic properties of a semiconductor are set by adjusting composition, crystal phase and morphology, {one|1|a single|one particular} {cannot|can’t|can not} {change|alter|modify|adjust|transform} them {anymore|any longer},…
The tetrazine/trans-cyclooctene ligation stands out {from the|in the} bioorthogonal toolbox {due to|because of|as a result of|on account of|resulting from|as a consequence of} its exceptional reaction kinetics, enabling {multiple|numerous|several|a number of|many|various}…
Protein-protein interactions play a {key|important|crucial|essential} {role|function|part} in cell homeostasis and physiological functions {of the|from the|in the|on the|with the|of your} organisms. Consequently, their malfunction {leads to|results in} {diseases|illnesses|ailments} {such as|like|including|for example|for…
{Throughout|All through} the history of chemistry, human efforts to {design|style|design and style} functional molecules have {caused|brought on|triggered} the discovery of {numerous|many|several|quite a few|a lot of|various} theories. {Recently|Lately|Not too long ago},…
Molecular-dynamics simulations are {used|utilized|employed|utilised|applied|made use of} for predictions {of the|from the|in the|on the|with the|of your} glass transition temperatures {for a|to get a|for any} test set of {5|five} aprotic ionic liquids.…
Electrolyte-gated transistors (EGTs) have emerging applications in physiological recording, neuromorphic computing, sensing, and {flexible|versatile} printed electronics. A challenge for these devices is their slow switching speed, which has {several|a number…
Photoswitchable reagents to modulate protein activity are {powerful|potent|effective|strong|highly effective} tools for high-spatiotemporal-precision {control|manage|handle} {over|more than} endogenous biological functions. TRPC5 {is a|is really a|is actually a|can be a|is often a|is usually…
Methylaluminoxane (MAO) is akey activator for olefin polymerization catalysts, {making|creating|producing|generating} its chemistry ofongoing interest. Neutral donors {such as|like|including|for example|for instance|which include} octamethyltrisiloxane (OMTS) areeffective abstractors {of the|from the|in the|on the|with…