Two diamond-shaped and partially fluorinated dehydrobenz[18]annulene macrocycles {have been|happen to be|have already been} synthesized {through|via|by means of|by way of} a one-pot synthesis relying on fourfold Sonogashira coupling. Single crystal structures {of the|from the|in the|on the|with the|of your} {prepared|ready} macrocycles show continuous columnar stacks {of these|of those} molecules {that are|which are|which can be|which might be|that happen to be} mediated by the fluoroarene–alkyne, arene–alkyne, fluoroarene–fluoroarene, and alkyne–alkyne [π···π] interactions {instead of|rather than|as opposed to|as an alternative to|in place of} the {expected|anticipated} fluoroarene–arene [π···π] interaction. Price of 2-Bromooxazole 1262412-13-4 Chemscene PMID:24189672
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