Ball milling mechanochemistry enables enables targeted, {rapid|fast|speedy} synthesis of mixed-metal metal-organic frameworks (MOFs) with controllable stoichiometric composition. {Specifically|Particularly|Especially}, {the use of|the usage of} ball milling enabled {the use of|the usage of} pre-assembled coordination polymers of zinc, magnesium, nickel(II) and cobalt(II) as precursors in an {innovative|revolutionary} mechanochemical {strategy|technique|method|approach|tactic} for the deliberate assembly of mixed-metal MOF-74 {materials|supplies|components} comprised of pairs of transition of {main|primary|principal|major|key|most important} group metals {in a|inside a|within a} pre-determinmed 1:1 stoichiometric ratio, {including|such as|which includes|like} ZnMg-, ZnCo, ZnCu, MgZn-, MgCo-, MgCa-, NiZn-,NiMg-, NiCo-, CoZn-, CoMg- and CoCu-MOF-74. {While|Whilst|Although|Even though|When|Though} {this is|this really is|this can be|that is} {the first|the very first|the initial} {example|instance} of target-oriented MOF synthesis {using|utilizing|making use of|employing|working with|applying} mechanochemistry, {it also|additionally, it|in addition, it} {provides|offers|gives|supplies|delivers} an entry to controlling the stoichiometric composition of mixed-metal frameworks. 7-Methyl[1,2,3]triazolo[1,5-a]pyridine site 1310405-06-1 web PMID:23903683
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