{A new|A brand new} class of CO-releasing molecules, M-CPOnes, was {prepared|ready} combining cyclopropenone-based ligands for CO release {with the|using the|with all the|together with the} modular scaffold of transition metal complexes. In proof-of-concept {studies|research}, M-CPOnes {based|primarily based} on ZnII, FeII and CoII are {stable|steady} {in the|within the|inside the} dark but undergo {efficient|effective} light-triggered CO release {with the|using the|with all the|together with the} cyclopropenone substituents and metal ions enabling tuning {of the|from the|in the|on the|with the|of your} photophysical properties. {Furthermore|Moreover|In addition|Additionally}, the {choice|option|selection|decision} of metal {allows|enables|permits|makes it possible for} {the use of|the usage of} {different|various|distinct|diverse|unique|distinctive} spectroscopic {methods|techniques|strategies|approaches|procedures|solutions} to monitor photodecarbonylation from fluorescence spectroscopy to UV/vis spectroscopy and paramagnetic NMR spectroscopy. The modularity of M CPOnes {from the|in the} metal ion {to the|towards the|for the} cyclopropenone substitution and {potential|possible|prospective} for {further|additional} functionalisation {of the|from the|in the|on the|with the|of your} ligand {makes|tends to make} M CPOnes {appealing|attractive} for tailored functionality in applications. 1286754-61-7 site 3-Chloro-4-hydroxybenzoic acid structure PMID:24428212
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