In {studies|research} aimed at {developing|creating|building|establishing} new organic spin {materials|supplies|components}, we {prepared|ready} a triisopropylsilylethynyl substituted tri(9-anthryl)methyl (TAntM) radical. The TIPS-ethynyl group {in this|within this} radical {effectively|successfully|efficiently|properly|proficiently|correctly} suppress its reactivity, resulting in {extremely|very|incredibly|really|particularly|exceptionally} {high|higher} stability in air for {at least|a minimum of|at the very least|at the least|no less than} {one|1|a single|one particular} month. Chemical modification {of the|from the|in the|on the|with the|of your} radical {using|utilizing|making use of|employing|working with|applying} [4+2] Diels-Alder reaction proceeds even at {room|space|area} temperature. {Because|Simply because|Since|Due to the fact|Mainly because|For the reason that} harsh {conditions|circumstances|situations} and metal-catalyzed reactions {are not|aren’t|usually are not|will not be|are certainly not|are usually not} {required|needed|necessary|essential|expected} this post-modification {strategy|technique|method|approach|tactic} {should|ought to|must|need to|really should|should really} be {highly|extremely|very|hugely} versatile for use in constructing {unique|distinctive|special|exclusive|exceptional|one of a kind} spin-labelled molecules. Buy883-40-9 Fmoc-β-HoGlu(OtBu)-OH web PMID:23724934
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