Living organisms can synthesize a wide {range of|selection of|array of} macromolecules from a {small|little|tiny|modest|smaller|compact} set of {natural|all-natural|organic} {building|developing|creating|constructing} blocks, {yet|however|but} {there is|there’s|there is certainly} {potential|possible|prospective} for even {greater|higher} {materials|supplies|components} diversity by exploiting biochemical processes to convert unnatural feedstocks into new abiotic polymers. {Ultimately|In the end|Eventually} the synthesis {of these|of those} polymers in situ {might|may|may well|may possibly|could|could possibly} {aid|help} the coupling of organisms with synthetic matrices, {and the|and also the|as well as the|along with the|plus the} generation of biohybrids or engineered living {materials|supplies|components}. The {key|important|crucial|essential} step in biohybrid {materials|supplies|components} preparation {is to|would be to|is always to|is usually to|will be to|should be to} harness the relevant biological pathways to {produce|create|generate|make} synthetic polymers with predictable molar masses and defined architectures {under|below|beneath} ambient {conditions|circumstances|situations}. Accordingly, we report an aqueous, oxygen-tolerant RAFT polymerization platform {based on|according to|depending on|determined by} a modified Fenton reaction {which is|that is|which can be} initiated by Cupriavidus metallidurans CH34, a bacterial species with iron {reducing|decreasing|lowering|minimizing} capabilities. We show the synthesis of a {range of|selection of|array of} water-soluble polymers {under|below|beneath} normoxic {conditions|circumstances|situations}, with {control|manage|handle} {over|more than} the molar mass distribution, {and also|as well as} the production of block copolymer nanoparticles {via|by way of|through|by means of} polymerization-induced self-assembly. {Finally|Lastly|Ultimately}, we highlight the {benefits|advantages|rewards|positive aspects|added benefits} of {using|utilizing|making use of|employing|working with|applying} a bacterial initiation {system|method|program|technique} by recycling the cells for {multiple|numerous|several|a number of|many|various} polymerisations. {Overall|General|All round}, our {method|technique|approach|strategy|system|process} represents a {highly|extremely|very|hugely} versatile {approach|method|strategy} to {producing|creating|generating|making} well-defined polymeric {materials|supplies|components} {within|inside} a hybrid natural-synthetic polymerization platform and in engineered living {materials|supplies|components} with properties beyond {those|these} of biotic macromolecules. Perfluoroundecanoic acid Chemscene 1612792-88-7 web PMID:24187611
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