The {potential|possible|prospective} of {strong|powerful|robust|sturdy} light-matter interactionsremains {to be|to become} {further|additional} explored {within|inside} a chemical context.Towards this {end|finish} we {here|right here} study the electromagneticinteraction {between|in between|among|amongst|involving} molecules and plasmonic nanocavities.By {means|indicates|implies|signifies|suggests} of electronic structure calculations, we show thatself-induced catalysis emerges {without|with out|without having|with no|devoid of|without the need of} any external drivingdue {to the|towards the|for the} interaction {of the|from the|in the|on the|with the|of your} molecular permanent andfluctuating dipole moments {with the|using the|with all the|together with the} plasmonic cavity modes.We also exploit this scheme to modify the transitiontemperature T1/2 of spin-crossover complexes as an exampleof how {one|1|a single|one particular} can {ultimately|in the end|eventually} {control|manage|handle} {materials|supplies|components} response throughstrong light-matter interactions. [Acr-Mes]+(ClO4)- custom synthesis 1349151-98-9 manufacturer PMID:23577779
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