Morita-Baylis-Hillman reaction employing N-alkylpyridinium salts as electrophiles has been {developed|created}. The reaction is promoted by DBU, which acts {both|each} as a catalyst activating the electron-poor olefin {as well|also|too|at the same…
We show that {strong|powerful|robust|sturdy} cation-anion interactions {in a|inside a|within a} wide {range of|selection of|array of} lithium-salt/ionic liquid mixtures {result in|lead to} a {negative|unfavorable|damaging|adverse} lithium transference {number|quantity}, {using|utilizing|making use of|employing|working with|applying}…
A versatile polyene cyclization {strategy|technique|method|approach|tactic} was {developed|created} that exploits conjugated -ionyl derivatives. Photomediated disruption {of the|from the|in the|on the|with the|of your} extended -system {within|inside} these chromophores unveils a contra-thermodynamic polyene…
High-throughput experiments (HTE) {enable|allow} {fast|quick|quickly|rapidly|rapid|speedy} exploration of {advanced|sophisticated} battery electrolytes {over|more than} vast compositional spaces. {Among|Amongst} the {multiple|numerous|several|a number of|many|various} properties {considered|regarded as|deemed|regarded|viewed as|thought of} for optimal electrolyte {performance|overall performance|efficiency|functionality},…
An optimized catalytic protocol for enantio- and diastereoselective reduction of racemic α-CF3, α-SCF3 and α-OCF3 aryl ketones is described. The reaction {involves|entails|requires|includes} a dynamic kinetic resolution (DKR) {based|primarily based} on…
Human immunodeficiency virus 1 (HIV-1) protease {is a|is really a|is actually a|can be a|is often a|is usually a} homo-dimeric aspartic protease {essential|important|crucial|vital|necessary|critical} for replication of HIV. The HIV-1 protease {is…