We show that {strong|powerful|robust|sturdy} cation-anion interactions {in a|inside a|within a} wide {range of|selection of|array of} lithium-salt/ionic liquid mixtures {result in|lead to} a {negative|unfavorable|damaging|adverse} lithium transference {number|quantity}, {using|utilizing|making use of|employing|working with|applying} molecular dynamics simulations and rigorous concentrated {solution|answer|remedy|resolution|option} theory. This behavior fundamentally deviates {from the|in the} {one|1|a single|one particular} obtained {using|utilizing|making use of|employing|working with|applying} self-diffusion coefficient {analysis|evaluation} and agrees {well|nicely|effectively|properly} with experimental electrophoretic NMR measurements, which accounts for ion correlations. We extend these findings to {several|a number of|numerous|many|various|quite a few} ionic liquid compositions. We investigate the degree of spatial ionic coordination employing single-linkage cluster {analysis|evaluation}, unveiling asymmetrical anion-cation clusters. {Additionally|In addition|Furthermore|Moreover|Also|On top of that}, we formulate a {way to|method to|approach to|strategy to|technique to|solution to} compute the {effective|efficient|successful|powerful|productive|helpful} lithium charge that corresponds to and agrees {well|nicely|effectively|properly} with electrophoretic measurements and show that lithium {effectively|successfully|efficiently|properly|proficiently|correctly} carries a {negative|unfavorable|damaging|adverse} charge {in a|inside a|within a} remarkably wide {range of|selection of|array of} chemistries and concentrations. The generality of our observation has {significant|substantial|considerable|important} implications for the {energy|power} storage {community|neighborhood}, emphasizing the {need|require|want|need to have|will need|have to have} to reconsider the {potential|possible|prospective} {of these|of those} systems as {next|subsequent} generation battery electrolytes. 1215071-12-7 In stock 1141886-37-4 web PMID:23671446
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