Prussian blue analogues (PBAs) have {recently|lately|not too long ago} shown outstanding electrochemical properties ascribable to their {unique|distinctive|special|exclusive|exceptional|one of a kind} open-framework crystal structure that {allows|enables|permits|makes it possible for} the reversible insertion of alkali ions with negligible perturbation {to the|towards the|for the} framework itself. {Many|Numerous|Several|A lot of|Quite a few|Lots of} hexacyanoferrate {materials|supplies|components} have shown {excellent|superb|outstanding|exceptional|great|fantastic} properties and are {some of the|a few of the|a number of the|several of the|many of the} most promising sodium- and potassium-ion cathode {materials|supplies|components} in {both|each} aqueous and organic electrolytes. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that}, {there is a|there’s a} distinct lack of candidate PBA {materials|supplies|components} that operate at low potentials as their characteristic crystalline framework shows instability. {In this|Within this} {article|post|write-up|report|short article} we characterise the structure and electrochemical behavior of manganese hexacyanochromate which exhibits reversible sodium insertion at – 0.86 V vs. SHE (1.84 V vs. Na+/Na), {whilst|while} {maintaining|sustaining|preserving|keeping} the characteristic PBA cubic structure. {This is|This really is|This can be|That is} the lowest redox {potential|possible|prospective} of reported PBA {materials|supplies|components} and shows {fast|quick|quickly|rapidly|rapid|speedy} kinetics {in a|inside a|within a} {high|higher} voltage water-in-salt electrolyte. {Further|Additional} reduction in {potential|possible|prospective} in an organic electrolyte shows decomposition {of the|from the|in the|on the|with the|of your} crystalline structure. 4-Formylbenzenesulfonyl chloride Chemscene 2-Chloro-6-methyl-5-nitronicotinonitrile Order PMID:23775868
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