{Despite|Regardless of|In spite of} {numerous|many|several|quite a few|a lot of|various} experimental and theoretical {studies|research} devoted {to the|towards the|for the} oxygen evolution reaction, the mechanism {of the|from the|in the|on the|with the|of your} OER on transition metal oxides remains controversial. {This is|This really is|This can be|That is} in {part|component|element|portion|aspect} owed {to the|towards the|for the} ambiguity of electrochemical parameters {of the|from the|in the|on the|with the|of your} mechanism {such as|like|including|for example|for instance|which include} the Tafel slope and reaction orders. We took {the most|probably the most|essentially the most|one of the most|by far the most} {commonly|generally|typically|frequently|normally|usually} assumed adsorbate mechanism and calculated the Tafel slopes and reaction orders with respect to pH {based on|according to|depending on|determined by} microkinetic {analysis|evaluation}. We demonstrate that {number|quantity} of {possible|feasible|achievable|attainable|doable|probable} Tafel slopes strongly {depends on|depends upon|is determined by|is dependent upon|will depend on} {a number of|numerous|several|quite a few|a variety of|many} preceding {steps|actions|measures|methods} and surface coverage. {Furthermore|Moreover|In addition|Additionally}, the Tafel slope becomes pH dependent when the coverage of intermediates {changes|modifications|adjustments|alterations} with pH. These insights complicate the identification of a rate-limiting step by a single Tafel slope at a single pH. {Yet|However|But}, simulations of reaction orders complementary to Tafel slopes can {solve|resolve} some ambiguities to distinguish {between|in between|among|amongst|involving} {possible|feasible|achievable|attainable|doable|probable} rate-limiting {steps|actions|measures|methods}. {The most|Probably the most|Essentially the most|One of the most|By far the most} insightful {information|info|details|data|facts|information and facts} {can be|may be|could be|might be|is often|is usually} obtained {from the|in the} low overpotential {region|area} {of the|from the|in the|on the|with the|of your} Tafel plot. The simulations {in this|within this} {work|function|perform|operate} {provide|offer|supply|give|present|deliver} clear {guidelines|recommendations|suggestions} to experimentalists for the identification {of the|from the|in the|on the|with the|of your} limiting {steps|actions|measures|methods} {in the|within the|inside the} adsorbate mechanism {using|utilizing|making use of|employing|working with|applying} the observed values {of the|from the|in the|on the|with the|of your} Tafel slope and reaction order in pH-dependent {studies|research}. Formula of (R)-3-Fluoropyrrolidine (hydrochloride) 1207625-15-7 Order PMID:36014399
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