{Current|Present|Existing} advances in molecular magnetism are aimed {at the|in the} {construction|building} of molecular nanomagnets and spin qubits for their utilization as high-density {data|information} storage {materials|supplies|components} and quantum {computers|computer systems}. Mononuclear coordination compounds with low spin values of S=½ are {excellent|superb|outstanding|exceptional|great|fantastic} candidates for this endeavour, but their {construction|building} {via|by way of|through|by means of} rational {design|style|design and style} is {limited|restricted}. This {particularly|especially|specifically} applies {to the|towards the|for the} single copper(II) spin center, {having|getting|possessing|obtaining} been only {recently|lately|not too long ago} demonstrated to exhibit slow relaxation of magnetisation {in the|within the|inside the} {appropriate|suitable|proper|acceptable} octahedral {environment|atmosphere}. {We have|We’ve|We’ve got} {thus|therefore|hence|as a result} {prepared|ready} a novel, modular organic scaffold that would {allow|permit|enable|let} {one|1|a single|one particular} to {gain|acquire|obtain|achieve|get} in-depth insight into how purposeful structural {differences|variations} {affect|impact|have an effect on|influence} the slow magnetic relaxation in monometallic, transition metal complexes. As a proof-of-principle, we demonstrate how {one|1|a single|one particular} can construct two, structurally {very|extremely|really|quite|incredibly|pretty} {similar|comparable|equivalent|related} complexes with isolated Cu(II) ions in an octahedral ligand {environment|atmosphere}, the magnetic properties of which differ {significantly|considerably|substantially|drastically}. The {differences|variations} in structural symmetry effects and in magnetic relaxation are corroborated {with a|having a|using a} series of experimental and theoretical {techniques|methods|strategies|tactics|approaches|procedures}, {showing|displaying} how symmetry distortions and crystal packing {affect|impact|have an effect on|influence} the relaxation behaviour in these isolated Cu(II) systems. Our {highly|extremely|very|hugely} modular organic platform {can be|may be|could be|might be|is often|is usually} {efficiently|effectively} utilized for the {construction|building} of {various|numerous|different|a variety of|several|many} transition-metal ion systems {in the|within the|inside the} future, {effectively|successfully|efficiently|properly|proficiently|correctly} {providing|supplying|offering|delivering|giving} a model {system|method|program|technique} for investigation of magnetic relaxation {via|by way of|through|by means of} targeted structural distortions. 2′-Deoxy-2′-fluoroadenosine site 846548-44-5 Purity PMID:24220671
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