Molecularly organized nanocomposites of polymers and carbon nanotubes (CNTs) have {great|fantastic|excellent|wonderful|good|terrific} {promise|guarantee} as high-performance {materials|supplies|components}; in {particular|specific|certain|distinct|unique}, conformal deposition of polymers can {control|manage|handle} interfacial properties for mechanical load transfer, electrical or thermal transport, or electro/chemical transduction. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that}, controllability of polymer-CNT interaction remains a challenge with {common|typical|frequent|widespread|prevalent|popular} processing {methods|techniques|strategies|approaches|procedures|solutions} that combine CNTs and polymers in melt or in {solution|answer|remedy|resolution|option}, {often|frequently|usually|typically|generally|normally} {leading|top|major} to non-uniform polymer distribution and/or aggregation of CNTs. {Here|Right here}, we demonstrate CNTs {within|inside} net-shape sheets {can be|may be|could be|might be|is often|is usually} controllably coated {with a|having a|using a} thin, conformal coating of meta-aramid by simultaneous capillary infiltration and interfacial polymerization. We {determine|figure out|decide|establish|ascertain|identify} that π interaction {between|in between|among|amongst|involving} the polymer and CNTs {results in|leads to} chain alignment parallel {to the|towards the|for the} CNT outer wall. Subsequent nucleation and {growth|development} {of the|from the|in the|on the|with the|of your} precipitated aramid {forms|types} a smooth continuous layered sheath {around|about} the CNTs. These findings motivate future investigation of mechanical and interfacial properties {of the|from the|in the|on the|with the|of your} resulting CNT composites, and adaptation {of the|from the|in the|on the|with the|of your} in-situ polymerization {method|technique|approach|strategy|system|process} to other substrates. 2170371-90-9 Price 887144-94-7 In stock PMID:24187611
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