Hybrid structures incorporating {different|various|distinct|diverse|unique|distinctive} organic and inorganic constituents are emerging as {a very|a really|an extremely|an incredibly} promising class of {materials|supplies|components} {since|because|given that|considering that|due to the fact|considering the fact that} they synergistically combine the complementary and diverse properties {of the|from the|in the|on the|with the|of your} {individual|person} {components|elements}. Hybrid {materials|supplies|components} {based on|according to|depending on|determined by} polyoxometalates (POMs) are {particularly|especially|specifically} {interesting|fascinating|intriguing|exciting} {due to|because of|as a result of|on account of|resulting from|as a consequence of} the versatile catalytic, redox, electronic, and magnetic properties of this {large|big|huge|massive|substantial|significant} {family|family members|loved ones|household} of metal-oxo clusters, {yet|however|but} the {combination|mixture} of {different|various|distinct|diverse|unique|distinctive} clusters has been scarcely reported. {Hence|Therefore}, herein we propose a novel and {general|common|basic} {strategy|technique|method|approach|tactic} for combining {multiple|numerous|several|a number of|many|various} {types of|kinds of|varieties of|forms of|sorts of} metal-oxo clusters {in a|inside a|within a} single hybrid molecule. Two novel hybrid POM structures (HPOMs) bis-functionalised with dipentaerythritol (R-POM1-R; R = (OCH2)3CCH2OCH2C(CH2OH)) {were|had been|have been} synthesised as building-blocks for the formation of heterometallic hybrid triads (POM2-R-POM1-R-POM2). Such a modular {approach|method|strategy} resulted {in the|within the|inside the} formation of {four|4} novel heterometallic hybrids combing the Lindqvist {V6}, Anderson-Evans {XMo6} (X = Cr or Al) and trisubstituted Wells-Dawson {P2V3W15} POM structures. Their formation was confirmed by multinuclear Nuclear Magnetic Resonance (NMR), infrared (IR) and UV-Vis spectroscopy, {as well|also|too|at the same time} as Mass Spectrometry, Diffusion Ordered Spectroscopy (DOSY) and elemental {analysis|evaluation}. Their thermal stability was also examined by Thermogravimetric {Analysis|Evaluation} (TGA), which showed that {overall|general|all round} the HPOM triads exhibit {higher|greater|larger} thermal stability than comparable hybrid structures containing only {one|1|a single|one particular} {type|kind|sort|variety|form} of POM. The one-pot synthesis {of these|of those} novel compounds was {achieved|accomplished} in {high|higher} yields in aqueous and organic media {under|below|beneath} {simple|easy|straightforward|basic|uncomplicated|very simple} reflux {conditions|circumstances|situations}, {without|with out|without having|with no|devoid of|without the need of} the {need|require|want|need to have|will need|have to have} of any additives, and {could be|might be|could possibly be|may be|may very well be} applied for {creating|making|producing|generating|developing|building} other hybrid {materials|supplies|components} {based on|according to|depending on|determined by} {a variety of|a number of|many different|various|a range of|several different} metal-oxo cluster building-blocks. Formula of 935845-20-8 886593-45-9 Chemscene PMID:24101108
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