{We have|We’ve|We’ve got} {designed|developed|created|made} and synthesized {a new|a brand new} curved π-conjugated molecule, 1,1-difluorosumanene (1), which possesses two fluorine atoms {on the|around the} {same|exact same|identical|very same|similar} benzylic carbon of unsubstituted…
Electrochemical N2 reduction (NRR) to ammonia is seriously {limited|restricted} by the competing hydrogen evolution reaction (HER) but atomic-scale {factors|elements|aspects|variables|components|things} controlling HER/NRR {competition|competitors} are unknown. Herein we unveil the mechanism, thermodynamics,…
ABSTRACTDye removal {using|utilizing|making use of|employing|working with|applying} low {cost|price|expense} adsorbent {is a|is really a|is actually a|can be a|is often a|is usually a} {suitable|appropriate} {method|technique|approach|strategy|system|process} for textile wastewater {treatment|therapy|remedy}. The aim of…
The sequence-specific hybridization of DNA facilitates its use as a {building|developing|creating|constructing} block for designer nanoscale structures and reaction networks that {perform|carry out|execute} computations. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that},…
We report the direct light activation of ethynylbenziodoxolone (EBX) reagents for the oxyalkynylation of aryl- and amino-cyclopropanes {as well|also|too|at the same time} as styrenes. Irradiation with visible light at 440…
Cost-effective production of green hydrogen is a major challenge for global adoption of a hydrogen economy. Technologies such as photoelectrochemical (PEC) or photocatalytic (PC) water splitting and photovoltaic + electrolysis…
We report experimental and computational {evidence|proof} for nitrogen–fluorine halogen bonding in Ag(I)-initiated radical C–H fluorinations. {Simple|Easy|Straightforward|Basic|Uncomplicated|Very simple} pyridines {form|type|kind} + halogen bonds with Selectfluor to facilitate single-electron reduction by catalytic…
{Once|As soon as|When|After} the optical, electronic or photocatalytic properties of a semiconductor are set by adjusting composition, crystal phase and morphology, {one|1|a single|one particular} {cannot|can’t|can not} {change|alter|modify|adjust|transform} them {anymore|any longer},…
The oxidation of alkenes by high-valent iron-oxo active species {normally|usually|typically|generally|commonly|ordinarily} {leads to|results in} the formation {of the|from the|in the|on the|with the|of your} corresponding epoxides. {Rarely|Seldom|Hardly ever}, carbonyl compounds are observed…
The tetrazine/trans-cyclooctene ligation stands out {from the|in the} bioorthogonal toolbox {due to|because of|as a result of|on account of|resulting from|as a consequence of} its exceptional reaction kinetics, enabling {multiple|numerous|several|a number of|many|various}…