Herein we report a novel chiral bismacrocycle with unexpected dual emission and tunable aggregation-induced emission colors. A facile four-step synthesis {strategy|technique|method|approach|tactic} is {developed|created} to construct this rigid bismacrocycle, (1,{4|four})cycloparaphenylenophane (SCPP),…
Carbon-fluorine bond activation reaction {of the|from the|in the|on the|with the|of your} trifluoromethyl group represent {an important|an essential|a crucial|a vital} {approach|method|strategy} to fluorine-containing molecules. {While|Whilst|Although|Even though|When|Though} selective defluorofunctionalization reactions of CF3-containing…
Electrochemical hydrogen evolution reaction (HER) at single graphene sheets has been investigated {widely|extensively|broadly} either in its pristine {form|type|kind} or {after|following|right after|soon after|immediately after|just after} chemical modification. {One|1|A single|One particular} {important|essential|crucial|critical|significant|vital}…
{Increasing|Growing|Escalating|Rising} usage of antimicrobials {is a|is really a|is actually a|can be a|is often a|is usually a} {significant|substantial|considerable|important} contributor {to the|towards the|for the} emergence and dissemination of antimicrobial resistance. Wastewater-based epidemiology…
Controlling the surface composition of colloidal nanoparticles {is still|continues to be} a {challenging|difficult} {yet|however|but} mandatory prerequisite in catalytic {studies|research} to investigate composition-activity trends, active {sites|websites|web sites|internet sites|web-sites|web pages}, and reaction…
Disordered and porous metal oxides are promising as earth-abundant and cost-effective {alternatives|options} to noble-metal electrocatalysts. Herein, we leverage non-saturated oxidation in plasma-enhanced atomic layer deposition to tune structural, mechanical, and…
{In the|Within the|Inside the} manuscript {the first|the very first|the initial} enantioselective dearomative Michael addition {between|in between|among|amongst|involving} α,β-unsaturated aldehydes and 2-nitrobenzofurans realized {under|below|beneath} N-heterocyclic carbene activation has been described. The reaction…
A series of bicyclic alkylamino carbenes (BICAAC) ({where|exactly where} N-aryl = dipp, mes, {2|two},6-dimethyl-4-(dimethylamino)phenyl, 5a-d) and their novel air- and moisture-resistant pyridine (pyridine, {4|four} dimethylaminopyridine) containing palladium PEPPSI-type Pd(II) complexes…
The production of hydrogen from water {via|by way of|through|by means of} solar water splitting {is a|is really a|is actually a|can be a|is often a|is usually a} {potential|possible|prospective} {method|technique|approach|strategy|system|process} to overcome…
Proteins are {an important|an essential|a crucial|a vital} class of biologics, but {there are several|there are many|there are numerous|there are lots of} recurring challenges to address when designing protein-based therapeutics. These…