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Formation of supramolecular nanostructures {via|by way of|through|by means of} in situ self-assembly and post-assembly modification of a biocatalytically constructed dipeptide hydrazide

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The in situ self-assembly of a biocatalytically constructed dipeptide hydrazide {gives|provides|offers} rise to supramolecular hydrogels, consisting of networks of supramolecular nanoarchitectures, {under|below|beneath} mild aqueous {conditions|circumstances|situations}. {Moreover|Furthermore|In addition|Additionally}, the post-assembly modification…

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Boosting efficiency in light-driven water splitting by dynamic irradiation {through|via|by means of|by way of} synchronizing reaction and transport processes

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This {work|function|perform|operate} elaborates the {effect|impact} of dynamic irradiation on light-driven molecular water oxidation to counteract catalyst deactivation. It highlights the {importance|significance|value} of {overall|general|all round} reaction engineering to overcome limiting {factors|elements|aspects|variables|components|things}…

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Orthogonal activation of metabotropic glutamate receptor {using|utilizing|making use of|employing|working with|applying} coordination chemogenetics

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Cell-surface receptors play a pivotal {role|function|part} as transducers of extracellular input. {Although|Even though|Though|Despite the fact that|While} {different|various|distinct|diverse|unique|distinctive} cell {types|kinds|varieties|sorts|forms} express {the same|exactly the same|the identical|precisely the same|the exact same} receptor,…

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Zinc-Mediated Hydroxyallylation of Aldehydes with Cyclopropanols: Direct Access to Vicinal anti-sec,tert-Diols {via|by way of|through|by means of} Enolized Homoenolate

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Direct and diastereoselective synthesis of vicinal anti-sec,tert-diols has been {achieved|accomplished} by zinc-mediated α- hydroxyallylation of aldehydes with cyclopropanols. The reaction {features|attributes|functions|characteristics|capabilities|options} the action of zinc enolized homoenolate, formed {via|by way…

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{High|Higher} harmonic spectra computed {using|utilizing|making use of|employing|working with|applying} time-dependent Kohn-Sham theory with Gaussian orbitals {and a|along with a|as well as a|plus a|and also a|in addition to a} {complex|complicated} absorbing {potential|possible|prospective}

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{High|Higher} harmonic spectra for H2 are simulated by solving the time-dependent Kohn-Sham equation {in the|within the|inside the} presence of a {strong|powerful|robust|sturdy} laser field, {using|utilizing|making use of|employing|working with|applying} an atom-centered Gaussian…

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Electrochemically Driven C-N Bond Formation from CO2 and Ammonia {at the|in the} Triple-Phase Boundary

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Electrosynthetic {techniques|methods|strategies|tactics|approaches|procedures} are gaining prominenceacross the fields of chemistry, engineering and {energy|power} science. {However|Nevertheless|Nonetheless|Even so|On the other hand|Having said that}, mostworks {within|inside} the {direction|path} of synthetic heterogeneous electrocatalysis {focus|concentrate} onwater…

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Time-Resolved Dynamics of {Stable|Steady} Open- and Closed-Shell Neutral Radical and Oxidized Tripyrrindione Complexes

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Decorating beads with paramagnetic rings: synthesis of inorganic-organic [10^14]rotaxanes as shown by spin counting

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The pH-dependent Swelling of Weak Polyelectrolyte Hydrogels Modeled at {Different|Various|Distinct|Diverse|Unique|Distinctive} Levels of Resolution

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A {Generally|Usually|Typically|Normally|Commonly|Frequently} Applicable Atomic-Charge Dependent London Dispersion Correction Scheme